Despite its acknowledged importance, the role of water in the genesis
of subduction zone volcanism is poorly understood. Amphibole dehydrati
on in subducting oceanic crust at a single pressure is assumed to gene
rate the water required for melting, but experimental constraints on t
he reaction are limited, and little attention has been paid to reactio
ns involving other hydrous minerals. Experiments on an oceanic basalt
at pressure-temperature conditions relevant to subducting slabs demons
trate that amphibole dehydration is spread over a depth interval of at
least 20 kilometers. Reactions involving other hydrous minerals, incl
uding mica, epidote, chloritoid, and lawsonite, also release water ove
r a wide depth interval, and in some subduction zones these phases may
transport water to deep levels in the mantle.