K. Kemp, APPORTIONMENT OF NON-PIXE SPECIES BY MEANS OF PIXE ANALYSIS, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 75(1-4), 1993, pp. 234-239
Source apportionment for air pollution by means of receptor models are
often used in connection with PIXE analysis. The origin of ''non-PIXE
'' species is assessed mainly by using PIXE based models. Three case s
tudies are discussed. 1) Soot is often used as general indicator for a
nthropogenic air pollution. The trend in the source contributions are
evaluated by including the measurements of soot on equal terms with mu
ltielement measurements in a factor model. Long range transport seems
to be the main reason for the increasing concentrations of soot in the
beginning of the 1980s. 2) A regression analysis is performed between
campaign measurements of the mutagenic activity of the aerosol in the
center of Copenhagen and the factor scores in a factor model based on
more than one year of daily measurements of multielement concentratio
n together with SO2, NO, NO2 and total particulates. It is shown that
traffic is the main source at street level, but that other local anthr
opogenic sources as well as long range transport contribute with compa
rable amounts. 3) A multipoint receptor model is used to show that loc
al sources as well as long range transport supplies the NO3- + HNO3 at
two sites in the southern part of Scandinavia, while no reasonable as
sessment of NO2 could be achieved.