METAL ION-LIGAND INTERACTIONS IN THERMOTROPIC LIQUID-CRYSTALS

Citation
Cl. Khetrapal et al., METAL ION-LIGAND INTERACTIONS IN THERMOTROPIC LIQUID-CRYSTALS, Journal of the Indian Chemical Society, 69(8), 1992, pp. 458-460
Citations number
5
Categorie Soggetti
Chemistry
ISSN journal
00194522
Volume
69
Issue
8
Year of publication
1992
Pages
458 - 460
Database
ISI
SICI code
0019-4522(1992)69:8<458:MIIITL>2.0.ZU;2-0
Abstract
Results on the studies of interactions of monovalent metal ions such a s Li+ and Ag+ in LiClO4, LiBF4 and AgNO2 with ligands like acetonitril e, dimethyl sulphoxide, pyridine and acetone in thermotropic liquid cr ystals are reported. They indicate the formation of metal ion-ligand a nd metal ion-liquid crystal complexes. At least two types of complexes for each metal ion-ligand have been detected. One of these is tetrahe dral, providing 'isotropic-like' spectra in the liquid crystalline med ia.