HGCL (B-X) CHEMILUMINESCENCE FROM ALKALI ATOM-HGCL2 REACTIONS

Citation
Jj. Wright et Lc. Balling, HGCL (B-X) CHEMILUMINESCENCE FROM ALKALI ATOM-HGCL2 REACTIONS, Spectroscopy letters, 26(4), 1993, pp. 689-692
Citations number
7
Categorie Soggetti
Spectroscopy
Journal title
ISSN journal
00387010
Volume
26
Issue
4
Year of publication
1993
Pages
689 - 692
Database
ISI
SICI code
0038-7010(1993)26:4<689:H(CFAA>2.0.ZU;2-O
Abstract
Laser action on the B2 SIGMA+1/2 --> X2 SIGMA+1/2 band of HgCl at 557. 6 nm (v' = 0 --> v'' = 22) has previously been achieved under a variet y of electronic and optical excitation mechanisms. This letter describ es a chemical mechanism for producing excited HgCl. We report on the g as phase reaction between alkali atoms (K, Rb, and Cs) and HgCl2 which produces HgCl (B-X) emission.