In this work, we discuss the design of an inorganic anti-reflective co
ating for use in photolithography at a wavelength of 3650 angstrom (I
line). We consider the effect of the optical constants on the reflecta
nce and show that when the extinction coefficient, k, of the film has
a value near 0.8, the reflectance will be very small for a range of va
lues of the thickness and the index of refraction, n. We illustrate th
e principle with one example where we use a combination of TiW and the
oxide of TiW. Reflectance is measured for a range of thicknesses of b
oth the TiW and the oxide of TiW. Values less than 5% were obtained.