HALIDE ANION RECOGNITION BY NEW ACYCLIC RUTHENIUM(II) BIPYRIDYL-POLYPYRIDINIUM RECEPTORS

Authors
BEER PD FLETCHER NC WEAR T
Citation
Pd. Beer et al., HALIDE ANION RECOGNITION BY NEW ACYCLIC RUTHENIUM(II) BIPYRIDYL-POLYPYRIDINIUM RECEPTORS, Inorganica Chimica Acta, 251(1-2), 1996, pp. 335-340
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
251
Issue
1-2
Year of publication
1996
Pages
335 - 340
Database
ISI
SICI code
0020-1693(1996)251:1-2<335:HARBNA>2.0.ZU;2-6
Abstract
New acyclic ruthenium(II) bipyridyl-pyridinium receptor molecules have been synthesised. H-1 NMR spectroscopy, and cyclic and square wave vo ltammetry have established these receptors complex and electrochemical ly sense the chloride anion. Disappointingly spectral detection of hal ide anions by electronic absorption and fluorescence-emission spectros copic measurements was unsuccessful.