Citation
J. Adamus et al., PHOTOCHEMICAL AND RADIOLYTIC CLEAVAGE OF 10-METHYLACRIDINE DIMER IN SOLUTIONS AND CRYOGENIC GLASSES, Journal of physical organic chemistry, 6(4), 1993, pp. 254-256
Citations number
9
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
08943230
Volume
6
Issue
4
Year of publication
1993
Pages
254 - 256
Database
ISI
SICI code
0894-3230(1993)6:4<254:PARCO1>2.0.ZU;2-K
Abstract
10-Methylacridine dimer [(AcrH)2)] dissociates into a pair of 10-methy
lacridyl radicals (AcrH.) on laser excitation (308 nm) in solvents of
various polarities. Exposure of (AcrH)2 in methylcyclohexane glass at
77 K to gamma-rays of Co-60 generates the radical cation (AcrH)2+. The
rmal annealing of the matrix to 90 K results in dissociation of (AcrH)
2+. into AcrH. and 10-methylacridinium cation (AcrH+).