POLYDISPERSITY CORRECTIONS FOR THE 2ND VIRIAL-COEFFICIENT

Authors
CONSTANTIN C SIMIONESCU BC SIMIONESCU CI
Citation
C. Constantin et al., POLYDISPERSITY CORRECTIONS FOR THE 2ND VIRIAL-COEFFICIENT, Revue Roumaine de Chimie, 37(11-12), 1992, pp. 1197-1204
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Revue Roumaine de Chimie → ACNP
ISSN journal
00353930
Volume
37
Issue
11-12
Year of publication
1992
Pages
1197 - 1204
Database
ISI
SICI code
0035-3930(1992)37:11-12<1197:PCFT2V>2.0.ZU;2-H
Abstract
The paper examined the influence of the molecular weight distribution types and the polydispersity index M(w)BAR/M(n)BAR of the values of th e second virial coeffcient determined by light scattering, for ultrahi gh molecular weight methyl methacrylatestyrene 50 : 50 random copolyme rs. It was observed that for M(w)BAR/M(n)BAR<2 the polydispersity corr ections for the second virial coefficient are not affecting the discus sion of the excluded volume effect.