SOLVOLYSES IN SUBSTITUTED CYCLOPROPYLCARBINYLIC SYSTEMS .2. SOLVOLYSIS OF 2'-METHYL-SPIRO[CYCLOPROPANE-1, 1'-INDANE]-2'-OL

Authors
RAZUS AC BUDA C GHIVIRIGA I PETRIDE A BARTHA E
Citation
Ac. Razus et al., SOLVOLYSES IN SUBSTITUTED CYCLOPROPYLCARBINYLIC SYSTEMS .2. SOLVOLYSIS OF 2'-METHYL-SPIRO[CYCLOPROPANE-1, 1'-INDANE]-2'-OL, Revue Roumaine de Chimie, 37(11-12), 1992, pp. 1291-1297
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Revue Roumaine de Chimie → ACNP
ISSN journal
00353930
Volume
37
Issue
11-12
Year of publication
1992
Pages
1291 - 1297
Database
ISI
SICI code
0035-3930(1992)37:11-12<1291:SISCS.>2.0.ZU;2-Z
Abstract
Solvolysis of the tertiary alcohol, 5a, in 1,4-dioxane-water in the pr esence of perchloric acid takes place mainly with water elimination. T he ring opening and ring enlargement also occurred, but in a small pro portion. In order to explain the observed behaviour, a reaction mechan ism was proposed.