NOVEL CYCLOADDITION REACTIONS OF METHACRYLOYL ISOCYANATE WITH ENAMINES

Authors
TSUGE O HATTA T MIZUGUCHI R KATO H
Citation
O. Tsuge et al., NOVEL CYCLOADDITION REACTIONS OF METHACRYLOYL ISOCYANATE WITH ENAMINES, Chemistry Letters, (4), 1993, pp. 631-634
Citations number
2
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
4
Year of publication
1993
Pages
631 - 634
Database
ISI
SICI code
0366-7022(1993):4<631:NCROMI>2.0.ZU;2-#
Abstract
Methacryloyl isocyanate (MAI) functioned as an ambident heterodiene in the cycloaddition reactions. Thus, enamines added not only to the acy l isocyanato moiety, but also to the enone moiety in MAI. Regiochemist ry of this cycloaddition markedly depended on the reaction conditions. The pathways for the formation of products are also described.