SYNTHESIS, ACID-BASE PROPERTIES, AND ELECTROCHEMICAL-BEHAVIOR OF PALLADIUM(II) COMPLEX WITH AMETHYLDIBENZO-[B,I][1,4,8,11]TETRAAZA[14]ANNULENE

Authors
RYZHIK GG VASILEV VV POPEKO IE SHAGISULTANOVA GA
Citation
Gg. Ryzhik et al., SYNTHESIS, ACID-BASE PROPERTIES, AND ELECTROCHEMICAL-BEHAVIOR OF PALLADIUM(II) COMPLEX WITH AMETHYLDIBENZO-[B,I][1,4,8,11]TETRAAZA[14]ANNULENE, Journal of applied chemistry of the USSR, 65(5), 1992, pp. 894-899
Citations number
10
Categorie Soggetti
Chemistry Applied
Journal title
Journal of applied chemistry of the USSR → ACNP
ISSN journal
0021888X
Volume
65
Issue
5
Year of publication
1992
Part
2
Pages
894 - 899
Database
ISI
SICI code
0021-888X(1992)65:5<894:SAPAEO>2.0.ZU;2-W
Abstract
An original method of synthesis of palladium(II) complex with ramethyl dibenzo[b,i][1,4,8,11]tetraaza[14]annulene (TMTAA) was presented and t he acid-base properties and electrochemical behavior of the compound w ere investigated. It was found that protonation and one-electron oxida tion are caused by elimination of one electron from the conjugated pi system of the chelate ring and cause the same type of changes in the e lectronic structure of the complex. It was shown that further electroo xidation of [PdTMTAA] causes the formation of a conducting polymer fil m on the electrode.