Av. Fokin et Ai. Rapkin, FLUOROSULFATION OF FLUOROALKYL HALIDES, Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences, 41(8), 1992, pp. 1329-1340
The basic characteristics of fluorosulfation of fluoroalkylhalides (ef
fect of the structure of the polyfluoroalkyl, nature of the halogen, a
cid catalysis, etc.) with halogen fluorosulfates and peroxydisulfuryl
difluoride were investigated. A mechanism was proposed for formation o
f fluorosulfonic acid fluoroalkyl esters based on the experimental and
quantum chemical data.