FLUOROSULFATION OF FLUOROALKYL HALIDES

Authors
FOKIN AV RAPKIN AI
Citation
Av. Fokin et Ai. Rapkin, FLUOROSULFATION OF FLUOROALKYL HALIDES, Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences, 41(8), 1992, pp. 1329-1340
Citations number
32
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences → ACNP
ISSN journal
10635211
Volume
41
Issue
8
Year of publication
1992
Part
1
Pages
1329 - 1340
Database
ISI
SICI code
1063-5211(1992)41:8<1329:FOFH>2.0.ZU;2-0
Abstract
The basic characteristics of fluorosulfation of fluoroalkylhalides (ef fect of the structure of the polyfluoroalkyl, nature of the halogen, a cid catalysis, etc.) with halogen fluorosulfates and peroxydisulfuryl difluoride were investigated. A mechanism was proposed for formation o f fluorosulfonic acid fluoroalkyl esters based on the experimental and quantum chemical data.