REACTION BETWEEN ISOPRENE AND ANILINE ON COMPLEX PALLADIUM CATALYSTS

Authors
PETRUSHKINA EA ZAKHARKIN LI
Citation
Ea. Petrushkina et Li. Zakharkin, REACTION BETWEEN ISOPRENE AND ANILINE ON COMPLEX PALLADIUM CATALYSTS, Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences, 41(8), 1992, pp. 1392-1394
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Russian Academy of Sciences, Division of Chemical Sciences → ACNP
ISSN journal
10635211
Volume
41
Issue
8
Year of publication
1992
Part
1
Pages
1392 - 1394
Database
ISI
SICI code
1063-5211(1992)41:8<1392:RBIAAO>2.0.ZU;2-N
Abstract
Isoprene and aniline have been reacted on the catalytic system Pd(acac )2-Ph3P to form a mixture of isomeric telomers: N-(dimethyloctadien-2, 7-yl-1)anilines and N-(dimethyloctadien-1,7-yl-3)anilines but on the c atalytic system Pd(acac)2-Ph3P-CF3COOH the main product is a mixture o f N-(methylbuten-2-yl)aniline adducts. The reaction between N-methylan iline and isoprene on the latter catalyst also gives a mixture of N-me thyl and N-(methylbuten-2-yl)aniline adducts.