CHEMICALLY MODIFIED ION-SENSITIVE FIELD-EFFECT TRANSISTORS - ELIMINATION OF THE LIQUID JUNCTION POTENTIAL IN A DOUBLE SENSOR FLOW-INJECTIONANALYSIS CELL
Plhm. Cobben et al., CHEMICALLY MODIFIED ION-SENSITIVE FIELD-EFFECT TRANSISTORS - ELIMINATION OF THE LIQUID JUNCTION POTENTIAL IN A DOUBLE SENSOR FLOW-INJECTIONANALYSIS CELL, Analytica chimica acta, 276(2), 1993, pp. 347-352
A flow-through cell was designed that can be used for flow-injection a
nalysis with two chemically modified ion-sensitive field-effect transi
stors (CHEMFETs) in close proximity. This offers the possibility of a
differential measurement without influence of the liquid junction pote
ntial. The differential signal of a potassium- and a sodium-selective
CHEMFET responded in a Nernstian manner and selectively towards potass
ium in an excess (fixed) concentration of sodium. A highly lead-select
ive CHEMFET was used in the same flow cell in combination with a potas
sium-selective CHEMFET.