THE SYNTHESIS, ELECTROCHEMISTRY AND THERMAL-PROPERTIES OF SOME MOLYBDENUM MONONITROSYL COMPLEXES CONTAINING OXOBIPHENYL LIGANDS WHICH INCORPORATE LONG-CHAIN ALKOXY SUBSTITUENTS

Authors
COE BJ JONES CJ MCCLEVERTY JA BRUCE DW
Citation
Bj. Coe et al., THE SYNTHESIS, ELECTROCHEMISTRY AND THERMAL-PROPERTIES OF SOME MOLYBDENUM MONONITROSYL COMPLEXES CONTAINING OXOBIPHENYL LIGANDS WHICH INCORPORATE LONG-CHAIN ALKOXY SUBSTITUENTS, Inorganica Chimica Acta, 206(1), 1993, pp. 41-46
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
206
Issue
1
Year of publication
1993
Pages
41 - 46
Database
ISI
SICI code
0020-1693(1993)206:1<41:TSEATO>2.0.ZU;2-9
Abstract
The new complexes Mo(NO)LX(OC6H4C6H4OR) (L = HB (3,5-Me2C3N2H)3; X = C l, I, OC6H4C6H4OR; R = C6H13, C8H17, C12H25) have been synthesised and characterised by spectroscopic methods. All undergo one-electron redu ction processes at potentials ranging from -0.28 V (SCE) for the mono- substituted complexes to -0.67 V for the bis-aryloxo compounds. Differ ential scanning calorimetry and hot-stage polarising microscopy studie s of these compounds do not reveal any liquid crystalline mesophases.