SYNTHESIS OF IMIDAZOLATE BRIDGED DINUCLEAR CU(II)-FE(III) PORPHYRINS

Authors
WANG R BREWER G
Citation
R. Wang et G. Brewer, SYNTHESIS OF IMIDAZOLATE BRIDGED DINUCLEAR CU(II)-FE(III) PORPHYRINS, Inorganica Chimica Acta, 206(1), 1993, pp. 117-121
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
206
Issue
1
Year of publication
1993
Pages
117 - 121
Database
ISI
SICI code
0020-1693(1993)206:1<117:SOIBDC>2.0.ZU;2-L
Abstract
Reaction of octaethylporphyriniron(III) perchlorate, Fe(oep)ClO4, or a n iron capped porphyrin perchlorate, Fe(C2cap)ClO4, with a copper(II) imidazolate complex, CuIm, gives the imidazolate bridged dinuclear mon oadducts, [Fe(oep)CuIm]ClO4 or [Fe(C2CaP)CuIM]ClO4, Which are characte rized by variable temperature magnetic susceptibility as spin coupled intermediate spin and admixed intermediate spin systems, respectively.