T. Hiraga et al., NONCRYSTALLINE CONDENSATION OF DENSELY DISSOLVED OPTICALLY NONLINEAR ORGANIC-COMPOUND IN POLYMER MATRICES, JPN J A P 1, 32(4), 1993, pp. 1722-1729
Optical properties and condensed states of the densely dissolved optic
ally nonlinear organic compound in polymer matrices were investigated
by means of optical measurements, structural analysis and pressure tun
ing spectroscopy. In the investigation of the absorption peak waveleng
th, 2-methyl-4-nitroaniline (MNA) in poly(methyl methacrylate) (PMMA)
exhibited characteristics intermediate between the crystal and the MNA
dissolved in solvents, i.e., noncrystalline condensation. This result
was consistent with those of X-ray diffraction analysis, second- and
third-harmonics generation, IR absorption and C-13-NMR spectroscopies.
It has also been revealed that such a system provides the most suitab
le measuring method of the third optical nonlinear constant for a vari
ety of compounds.