Deep-level transient spectroscopy (DLTS) has been employed to study gr
own-in point defects in vapour phase epitaxial layers of GaAs0.6P0.4:
Te. It was found that for the Ga-rich vapour phase three electron trap
s T1 (0.20 eV), T2 (0.18 eV) and T3 (0.38 eV) are formed. The traps T1
and T2 were found to be donor-related and are tentatively identified
as Te(As)GA(As)Te(As) and O(i)Te(As) complexes, respectively. The trap
T3 was found to be dependent on the dislocation density and it is pos
sibly associated with either an As or P vacancy generated by the incre
ase in misfit dislocations. A detrimental effect of these defects on t
he radiative recombination efficiency is shown. Under an excess of the
group V elements in the vapour phase, only one electron trap T4 (0.18
eV) was observed.