Wl. Holstein et al., EFFECT OF SINGLE-CRYSTAL SUBSTRATES ON THE GROWTH AND PROPERTIES OF SUPERCONDUCTING TL2BA2CACU2O8 FILMS, Journal of materials research, 8(5), 1993, pp. 962-972
Superconducting Tl2Ba2CaCu2O8 films were prepared by a two-step postde
position anneal process under identical conditions on a number of sing
le crystal substrates: (100) LaAlO3, (100) NdGaO3, (100) LaGaO3, (100)
SrTiO3, (100) MgO, and (0001) Al2O3. The properties of the resulting
Tl2Ba2CaCu2O8 films were strongly dependent on the substrate. Films on
all substrates were predominantly c-axis oriented. Films prepared on
LaAlO3, NdGaO3, and LaGaO3 also exhibited in-plane epitaxy, while film
s on MgO, Al2O3, and SrTiO3 were not aligned with the substrates. Some
a-axis oriented grains of Tl2Ba2CaCu2O8 formed on NdGaO3 and both a-a
xis oriented grains and cracks were present on LaGaO3. Large amounts o
f secondary phases, as indicated by additional peaks in the x-ray diff
raction scans, were observed for films on Al2O3 and SrTiO3 and smaller
amounts on each of the other substrates. Depth profiling by sputtered
neutral mass spectroscopy (SNMS) confirmed the presence of strong fil
m-substrate reactions on Al2O3 and SrTiO3, and also indicated the pres
ence of a reaction on NdGaO3. The T(c) onset of the films as measured
both inductively and by ac magnetic susceptibility varied depending on
the substrate. The highest quality films were prepared on LaAlO3. NdG
aO3 may also prove to be an acceptable substrate if the nucleation and
growth of a-axis oriented Tl2Ba2CaCu2O8 grains can be eliminated. The
remaining substrates appear to be less suitable due to severe film-su
bstrate interactions, lack of epitaxial growth, or crystallographic ph
ase changes.