El. Hall et Am. Ritter, STRUCTURE AND BEHAVIOR OF METAL CERAMIC INTERFACES IN TI ALLOY SIC METAL-MATRIX COMPOSITES/, Journal of materials research, 8(5), 1993, pp. 1158-1168
The structure and mechanical behavior of the fiber/matrix interface in
Ti alloy/SCS-6 SiC metal matrix composites were studied. In these com
posites the interface region consists of a fiber-coating region and a
metal reaction zone between the SiC fiber body and the metal matrix. T
he fiber coating consists of a number of zones or layers which are com
prised of cubic SiC particles in a turbostratic carbon matrix. Some am
biguity remains, concerning the number of distinct layers and the size
, shape, and density of the SiC particles. The effect of composite fab
rication and heat treatment on the coating structure is relatively sma
ll. Studies of the metal reaction zone adjacent to the fiber in Ti all
oy/SCS-6 SiC MMC's have shown that a number of discrete zones or layer
s form. Nearest the fiber, a zone of cubic TiC occurs, with increasing
grain size with distance from the fiber. Nearest the metal matrix, a
zone of Ti5Si3 forms. In high Al content alloys, an intermediate zone
forms that consists of Ti2AlC or Ti3AlC. The fiber/matrix interface pl
ays an important role during transverse tensile loading of these compo
sites. The tensile behavior is controlled by debonding at the interfac
e, followed by deformation of the matrix ligaments. Replica observatio
ns show that the debonding initiates and propagates within the coating
layers, but is not confined to a single layer interface.