Rj. Gooding et Jr. Morris, ABSENCE OF ENHANCED FLUCTUATIONS AS A 1ST-ORDER PHASE-TRANSITION IS APPROACHED - AN EXACT TRANSFER-MATRIX STUDY, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 47(4), 1993, pp. 2934-2937
As a second-order phase transition is traversed critical scattering ap
pears; these fluctuations serve notice of the impending loss of stabil
ity of the equilibrium phase. For a model first-order phase transition
we rigorously prove, using exact thermodynamic quantities obtained fr
om strip-transfer-matrix calculations, as well as finite-size-scaling
analysis, that as a temperature-driven, symmetry-breaking, first-order
phase transition is approached, no enhancement of fluctuations into t
he future product phase occurs. To be specific, we study the probabili
ty of occupation of the product phase (stable below the transition tem
perature), and demonstrate that this is a monotonically decreasing fun
ction as the transition temperature is approached from above. The rela
tion of this pedagogical result to x-ray scattering experiments is dis
cussed.