Microstructural studies play an important role in establishing the rel
ation between composition, processing and final properties of many foo
d products. In order to arrive at a full description of microstructure
many visualization- and preparation techniques are needed. A number o
f fatty products such as shortenings, margarine, butter, and low fat s
preads are discussed from a microstructural point of view. Examples of
the influence of process parameters on microstructure and rheological
properties are given. In particular, attention is paid to the fat cry
stalline matrix and the emulsion structure. Further, a new methodology
is described making it possible to study interactions of emulsifiers
at interfaces between oil and water. In this context, the displacement
, at a planar interface, of sodium caseinate by low-molecular mass emu
lsifiers such as monoacylglycerols and phospholipids has been studied.
It appears that saturated monoacylglycerols are more active in displa
cing the protein than unsaturated monoacylglycerols. With phospholipid
s, complicated phenomena such as spontaneous emulsification, occur at
the oil/water interface. Phospholipids, in general, appear to be much
more surface-active than monoacylglycerols. This type of work generate
s ideas to control and manipulate the microstructure and product prope
rties of fatty products.