TOTAL SYNTHESIS OF (+ -)-SARCOPHYTOL-M

Authors
LI YL YUE YJ XING YC
Citation
Yl. Li et al., TOTAL SYNTHESIS OF (+ -)-SARCOPHYTOL-M, Tetrahedron letters, 34(17), 1993, pp. 2799-2800
Citations number
4
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
17
Year of publication
1993
Pages
2799 - 2800
Database
ISI
SICI code
0040-4039(1993)34:17<2799:TSO(->2.0.ZU;2-4
Abstract
The total synthesis of (+/-)-sarcophytol-M, a marine cembranol, was fi rst achieved from geraniol through twelve steps by using intramolecula r nucleophilic addition of sulfur-stabilized carbanion to ketone as th e key step.