REACTION OF 2,3-0-ISOPROPYLIDENE-D-GLYCERALDEHYDE AND SOME DIALKYL AND DIARYLTHIOMETHYL SULFOXIDES - STEREOCHEMICAL ASPECTS

Authors
SASTRE JAL AMO JFR SANZ JMB MOLINA JM ROMEROAVILA MC TEJEDOR AS GONZALEZ DG
Citation
Jal. Sastre et al., REACTION OF 2,3-0-ISOPROPYLIDENE-D-GLYCERALDEHYDE AND SOME DIALKYL AND DIARYLTHIOMETHYL SULFOXIDES - STEREOCHEMICAL ASPECTS, Journal of carbohydrate chemistry, 12(3), 1993, pp. 291-308
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology
Journal title
Journal of carbohydrate chemistry → ACNP
ISSN journal
07328303
Volume
12
Issue
3
Year of publication
1993
Pages
291 - 308
Database
ISI
SICI code
0732-8303(1993)12:3<291:RO2ASD>2.0.ZU;2-J
Abstract
The reaction of 2,3-O-isopropylidene-D-glyceraldehyde with different d ialkyl and diarylthiomethyl sulfoxides occurs with a high selectivity and produces the corresponding 1-alkyl(or 1-aryl)-sulfynil-1-alkyl(or 1-aryl) thio-3,4-O-isopropylidene-D-tetroses as pure diastereoisomers. We have determined the absolute configuration of the three chiral cen ters formed in these reactions.