MAGNETIC INTERACTION OF IRON(II)-IRON(III) COMPLEXES WITH CARBOXYLIC-ACID

Authors
MAEDA Y TANIGAWA Y HAYAMI S TAKASHIMA Y
Citation
Y. Maeda et al., MAGNETIC INTERACTION OF IRON(II)-IRON(III) COMPLEXES WITH CARBOXYLIC-ACID, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 76(1-4), 1993, pp. 59-60
Citations number
10
Categorie Soggetti
Physics, Nuclear","Nuclear Sciences & Tecnology","Instument & Instrumentation
Journal title
Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms → ACNP
ISSN journal
0168583X
Volume
76
Issue
1-4
Year of publication
1993
Pages
59 - 60
Database
ISI
SICI code
0168-583X(1993)76:1-4<59:MIOICW>2.0.ZU;2-J
Abstract
Diiron(II)-(III) complexes [Fe2L(B)2](X)2 are prepared, where HL repre sents s[bis(2-pyridylmethyl)aminomethyl]-4-methylphenol, HB is carboxy lic acid or dicarboxylic acid, and X is ClO4- or BF4-. The valence sta te of the irons of some complexes is delocalized in the Mossbauer time scale (1 x 10(-7) s) at 296 K and localized at 78 K. The valence stat e of the irons of the other complexes is localized at the temperature range of 78-296 K.