Pv. Hendriksen et al., VIBRATIONS OF CARBON-SUPPORTED ULTRAFINE IRON-OXIDE PARTICLES, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 76(1-4), 1993, pp. 221-222
Carbon-supported 5 nm iron oxide particles have been studied by use of
Mossbauer Spectroscopy. It is found that the spectral area decreases
rapidly with increasing temperature and the temperature dependence of
its logarithm is linear above 5 K. This indicates that particle vibrat
ions give an important contribution to the mean square amplitude of th
e atoms. After wetting the sample with water the logarithm of the area
still varies linearly with temperature, but the slope is reduced cons
iderably. This indicates that the formation of ice around the particle
s reduces the particle vibrations.