SB-121 MOSSBAUER SPECTROSCOPIC STUDY OF THE MINERAL STIBICONITE

Citation
Jg. Stevens et al., SB-121 MOSSBAUER SPECTROSCOPIC STUDY OF THE MINERAL STIBICONITE, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 76(1-4), 1993, pp. 252-253
Citations number
2
Categorie Soggetti
Physics, Nuclear","Nuclear Sciences & Tecnology","Instument & Instrumentation
ISSN journal
0168583X
Volume
76
Issue
1-4
Year of publication
1993
Pages
252 - 253
Database
ISI
SICI code
0168-583X(1993)76:1-4<252:SMSSOT>2.0.ZU;2-0
Abstract
Stibiconite is a naturally occurring antimony mineral. Studied in this investigation are five samples using Sb-121 Mossbauer spectroscopy. T he relative amounts of the oxidation states Sb(III) and Sb(V) are dete rmined with the ratio of Sb(III) to Sb(V) varying from 0.03 to 0.6. Th e Mossbauer data collected for these samples along with elemental anal ysis, provide a better understanding of the structure and composition of these minerals. A new chemical formula for stibiconite is proposed: Ca4xSb(III)3-8xSb(V)1+4x(O,OH,H2O)y.