DEPTH DEPENDENT MOSSBAUER-SPECTROSCOPY OF QUENCHED SLAGS

Authors
MCCAMMON CA CHASKAR V RICHARDS GG
Citation
Ca. Mccammon et al., DEPTH DEPENDENT MOSSBAUER-SPECTROSCOPY OF QUENCHED SLAGS, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 76(1-4), 1993, pp. 428-430
Citations number
5
Categorie Soggetti
Physics, Nuclear","Nuclear Sciences & Tecnology","Instument & Instrumentation
Journal title
Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms → ACNP
ISSN journal
0168583X
Volume
76
Issue
1-4
Year of publication
1993
Pages
428 - 430
Database
ISI
SICI code
0168-583X(1993)76:1-4<428:DDMOQS>2.0.ZU;2-P
Abstract
Fe-57 Mossbauer spectra were recorded at room temperature of six quenc hed slags in the system FeO-Fe2O3-CaO-Al2O3-SiO2 at depths of 10 mum, 250 mum and 1000 mum from the surface. The Fe3+ composition decreases as a function of depth in CaO-containing slags, while it increases wit h depth when no CaO is present. The mean isomer shift of Fe2+ is essen tially constant with both bulk composition and depth, while the mean F e2+ quadrupole splitting increases substantially with bulk iron conten t and shows large depth dependence in slags synthesized at Fe saturati on.