A NEW METHOD FOR THE SYNTHESIS OF 2-GLYCOSYLAMINOPYRIDINES - TANDEM DIELS-ALDER RETRO-DIELS-ALDER REACTIONS IN THE SYNTHESIS OF 2-AMINO AND2-GLYCOSYLAMINOPYRIDINES

Authors
COBO J MELGUIZO M SANCHEZ A NOGUERAS M
Citation
J. Cobo et al., A NEW METHOD FOR THE SYNTHESIS OF 2-GLYCOSYLAMINOPYRIDINES - TANDEM DIELS-ALDER RETRO-DIELS-ALDER REACTIONS IN THE SYNTHESIS OF 2-AMINO AND2-GLYCOSYLAMINOPYRIDINES, Synlett, (4), 1993, pp. 297-299
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
4
Year of publication
1993
Pages
297 - 299
Database
ISI
SICI code
0936-5214(1993):4<297:ANMFTS>2.0.ZU;2-I
Abstract
Several 2-amino and 2-glycosylaminopyridines, 3 and 7, were synthesize d through a tandem Diels-Alder/Retro Diels-Alder reaction starting fro m 6-amino and 6-glycosylamino pyrimidines, 1 and 6, with dimethyl acet ylenedicarboxylate (DMAD), 2, as dienophile. This approach constitutes a new method for the synthesis of nucleosides derived from 2-amino py ridines.