P. Fotland et al., DETECTION OF ASPHALTENE PRECIPITATION AND AMOUNTS PRECIPITATED BY MEASUREMENT OF ELECTRICAL-CONDUCTIVITY, Fluid phase equilibria, 82, 1993, pp. 157-164
Asphaltene deposition during oil production might lead to expensive cl
ean up operations. The production plans may also have to be reviewed.
It is therefore necessary to investigate the potential for asphaltene
deposition prior to field development. Reliable techniques for detecti
on of asphaltene precipitation are needed in order to test existing th
eoretical models. The available experimental techniques are elaborate
and not suited for high pressure work. A novel technique to determine
asphaltene precipitation and relative amounts precipitated is presente
d. The technique is based on measurement of electrical conductivity, o
f the crude oil. It is seen that the electrical conductivity changes a
bruptly at the point of precipitation. Both gravimetric analysis and m
icroscopy has been used to verify the results obtained by conductivity
. The principle has been checked for a number of oils with varying asp
haltene content from 0.3wt% to 9wt%. Results from four different oils
are reported.