Alloys based on Fe3Al have an equilibrium DO3 Structure at low tempera
tures and transform to a B2 structure above about 550-degrees-C. The i
nfluence of different rates of quenching from the B2 region to room te
mperature and of subsequent heat treatments on the microstructure and
mechanical properties of powder metallurgy (P/M) alloys with two diffe
rent chromium contents have been examined. Optimizing the processing t
o maximize the amount of B2 order, without eliminating dislocations th
at enhance both strength and ductility, yields room-temperature ductil
ity approaching 20%, although the fracture mode is primarily brittle c
leavage. The B2 structure generally has lower flow stress than the DO3
structure because of its lower strain-hardening rate, although B2 ord
er actually has higher yield strength when the structure is free of di
slocations. Increasing the chromium content from 2% to 5% has little e
ffect on ductility, although the 2% Cr alloys generally have higher yi
eld strengths and larger order parameters.