Silcretes developed within the in situ regolith in the Barr Smith Rang
e, western Australia, were investigated using optical and electron-bea
m techniques. One of the cementing agents in these silcretes showed ge
l-like optical properties and had a variable aluminosilicate chemical
composition at the scale of electron microprobe analysis so that it mi
ght be considered as allophane-like material. High resolution transmis
sion electron microscopy demonstrated that the material consists of a
fine-grained and poorly ordered kaolinite embedded in a matrix of amor
phous silica.