SYNTHESIS OF CERTAIN MULTIDENTATE BENZIMIDAZOLE-DERIVED LIGANDS

Authors
SIVAGNANAM U PANDIYAN T PALANIANDAVAR M
Citation
U. Sivagnanam et al., SYNTHESIS OF CERTAIN MULTIDENTATE BENZIMIDAZOLE-DERIVED LIGANDS, Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry, 32(5), 1993, pp. 572-576
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Indian journal of chemistry. Sect. B: organic chemistry, including medical chemistry → ACNP
ISSN journal
03764699
Volume
32
Issue
5
Year of publication
1993
Pages
572 - 576
Database
ISI
SICI code
0376-4699(1993)32:5<572:SOCMBL>2.0.ZU;2-5
Abstract
Synthetic procedures are described for obtaining various multidentate ligands incorporating benzimidazole moieties. The benzimidazoles were obtained by the condensation of acids with o-phenylenediamines. Synthe ses are reported for N,N-bis (1-methylbenzimidazol-2-ylmethyl)amine (2 ), N,N'-bis (1-methylbenzimidazol-2-ylethyl)ethylenediamine (5), N,N,N ',N'- tetrakis (benzimidazol- 2-ytmethyl)- 1,2-diaminocyclohexane (6), N,N,N',N'-tetrakis hylbenzimidazol-2-ylmethyl)-1,2-diaminocyclohexane (7), HOOC-(CH2)m-S-CH2-CH2-S-(CH2)n-S- CH2-CH2-S-(CH2)m-COOH [where n = 2, m = 1(8); n = 2, m = 2 (10); n = 3, m = 1 (12)], BzIm-(CH2m- S-C H2-CH2-S- (CH2)n-S-CH2-CH2-S-(CH2)m-BzIm [where n = 2, m = 1 (9); n = 2, m = 2 (11); n = 3, m = 1 (13); n = 3, m = 2 (14) and BzIm = benzimi dazol-2-yl], HOOC-CH2-S-CH2-CH2-S)4- CH2-COOH (15) and BzIm-CH2-S-(CH2 -CH2-S)4-CH2-BzIm (16).