T. Asokan et Ts. Sudarshan, SPECTRAL NATURE OF LUMINOSITY ASSOCIATED WITH THE SURFACE FLASHOVER PROCESS, IEEE transactions on electrical insulation, 28(2), 1993, pp. 192-199
Investigations of the luminous events associated with the break-down a
long the surfaces of large band gap insulators such as polycrystalline
alumina and monocrystalline quartz in vacuum were made by employing a
phototube and a very sensitive photomultiplier tube (PMT). The onset
of luminous signals, in general, was found to start much before the on
set of voltage collapse during breakdown. The early onset of luminosit
y may be due to the presence of various defect or trapping centers wit
hin the forbidden gap of the insulator. The spectral nature of the lig
ht emitted during breakdown was resolved (in terms of the wavelength)
by interfacing a monochromator with the PMT. In the case of the monocr
ystalline quartz specimen, the breakdown luminosity was observed to be
associated with the defects located at 2.76 and 1.91 eV below the con
duction band edge. The breakdown luminosity of polycrystalline alumina
was found to be associated with the defects corresponding to energy l
evels at approximately 1.91, 2.25, 2.45 and 2.76 eV. The formation of
these defects is discussed in terms of the nonstoichiometric nature of
the lattice structure at the surface. Besides, the samples were found
to emit light when no breakdown occurs. This no-breakdown light emiss
ion was found to be attributed to the deep level defects. The observed
results suggest that the surface flashover process is primarily contr
olled by the defect or trapping centers located within the forbidden g
ap of the insulators.