The partitioning of manganese and silicon at the cementite/ferrite int
erface during the tempering process of Fe-C-Si-Mn martensite has been
studied by atom probe field ion microscopy. The results from early sta
ges of tempering indicate that cementite can form without partitioning
of silicon and manganese and appears to be controlled by carbon diffu
sion in the matrix. The onset of a significant redistribution of both
silicon and manganese occurs after extended tempering. Two-step temper
ing led to extensive partitioning of manganese and silicon.