STRUCTURES OF BIS(CYCLOPENTADIENYL) BINUCLEAR TITANIUM COMPLEXES

Authors
MKOYAN SG ALIEV ZG URAZOVSKII IF ATOVMYAN LO NIFANTEV IE BUTAKOV KA
Citation
Sg. Mkoyan et al., STRUCTURES OF BIS(CYCLOPENTADIENYL) BINUCLEAR TITANIUM COMPLEXES, Russian chemical bulletin, 45(9), 1996, pp. 2154-2156
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
9
Year of publication
1996
Pages
2154 - 2156
Database
ISI
SICI code
1066-5285(1996)45:9<2154:SOBBTC>2.0.ZU;2-9
Abstract
The (C5H4-XMe(2)-C5H4).(TiCl3)(2) binuclear complexes, where X = Si (1 ) or C (2), have been studied by X-ray structural analysis. In both st ructures, the coordination polyhedra about the Ti atoms are distorted tetrahedra formed by three Cl atoms and one Cp ring. The conformations of molecules 1 and 2 and the possibility of the occurrence of seconda ry Ti--Cp...Cl-Ti interaction are discussed.