PERI-NAPHTHYLENEDIAMINES .18. 1,8-BIS(DIMETHYLAMINO)-4-VINYLNAPHTHALENE

Citation
Nv. Vistorobskii et Af. Pozharskii, PERI-NAPHTHYLENEDIAMINES .18. 1,8-BIS(DIMETHYLAMINO)-4-VINYLNAPHTHALENE, Russian chemical bulletin, 45(9), 1996, pp. 2181-2183
Citations number
9
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10665285
Volume
45
Issue
9
Year of publication
1996
Pages
2181 - 2183
Database
ISI
SICI code
1066-5285(1996)45:9<2181:P.1>2.0.ZU;2-3
Abstract
The 1-[1,8-bis(dimethylamino)-4-naphthyl]ethyl carbocation generated f rom the corresponding alcohol in benzene in the presence of Al2O3 unde rgoes elimination according to the El mechanism to give previously unk nown 1,8-bis(dimethylamino)-4-vinylnaphthalene in a good yield: This c ompound was also synthesized from 1,8-bis(dimethylamino)4-formylnaphth alene by the Wittig reaction. Polymerization of the vinylic derivative obtained was studied.