H. Fukuda et al., EFFECT OF DEUTERIUM ANNEAL ON SIO2 SI(100) INTERFACE TRAPS AND ELECTRON-SPIN-RESONANCE SIGNALS OF ULTRATHIN SIO2-FILMS/, JPN J A P 2, 32(4B), 1993, pp. 569-571
Anneal kinetics of the SiO2/Si(100) interface defects of 5-nm-thick Si
O2 films have been investigated through comparison of the electron spi
n resonance (ESR) center with the interface trap density D(it). The ES
R signal showed two distinct defects (so-called P(b0) and P(b1)) at th
e SiO2/Si(100) interface: These P(b0) and P(b1) defects are annihilate
d by a low-temperature (500-degrees-C) deuterium (D2) anneal. By contr
ast, the D2 anneal at 900-degrees-C causes an increase in the number o
f the defects after a decrease at the initial stage (< 10 s). We concl
ude that there are annihilation and dissociation processes causing the
P(b0) and P(b1) defects, dependent on the D2 anneal time and temperat
ure.