S. Kawamoto et al., VALENCE-BAND DENSITY OF STATES OF PALLADIUM SILICIDES STUDIED BY X-RAY-EMISSION SPECTROSCOPY (XES), JPN J A P 2, 32(4B), 1993, pp. 597-600
The valence band (VB) electronic state of the transition metal silicid
es, Pd2Si and PdSi, is studied by X-ray emission spectroscopy (XES), a
nd it is proposed that the Si(s) electronic state is present near the
Fermi edge of the VB density of states (VB-DOS) of Pd silicides. This
conclusion is in clear contrast to a previous proposal, where it is cl
aimed that the upper part of the valence band of transition metal sili
cide consists only of Si(3p)-metal(d) hybridized states.