Microroughness of mechanochemically polished (100) silicon surfaces ha
s been determined from X-ray reflectivity data. An optical interferome
ter showed equally smooth surfaces (3 approximately 4 angstrom rms) fo
r all samples examined. X-ray Fresnel reflectivity data revealed disti
nct decay features of the scattering profiles from samples polished us
ing different relative strengths of mechanical and chemical factors. P
rofile fits were used to evaluate the Gaussian rms roughness at 11 app
roximately 12 angstrom under oxide layers of a density close to 2.0 g/
cm3. A stoichiometry not far from that of SiO2 was found for the overl
ayer oxide.