ACYLATION OF ALIPHATIC DIAMINES WITH METHYL NITROACETATE

Authors
LYAPKALO IM IOFFE SL STRELENKO YA TARTAKOVSKY VA
Citation
Im. Lyapkalo et al., ACYLATION OF ALIPHATIC DIAMINES WITH METHYL NITROACETATE, Russian chemical bulletin, 45(9), 1996, pp. 2245-2247
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
45
Issue
9
Year of publication
1996
Pages
2245 - 2247
Database
ISI
SICI code
1066-5285(1996)45:9<2245:AOADWM>2.0.ZU;2-R
Abstract
N,N'-Bis(nitroacetyl)diamines were synthesized for the first time by t he reaction of methyl nitroacetate with aliphatic diamines in H2O or E tOH in the presence of pyridine or imidazole. In the case of 1,2-ethyl enediamine, the N-mononitroacetyl derivative was isolated as an interm ediate product.