SUBSTITUTION-REACTIONS OF [CUI(ASPH3)3X] (X = CL, BR OR I) WITH 3-PHENYL-2-THIOXOIMIDAZOLIDIN-4-ONE (PTIH) AND 5-MERCAPTO-1-PHENYL-1,2,3,4-TETRAZOLE (MPTH)
R. Singh et Sk. Dikshit, SUBSTITUTION-REACTIONS OF [CUI(ASPH3)3X] (X = CL, BR OR I) WITH 3-PHENYL-2-THIOXOIMIDAZOLIDIN-4-ONE (PTIH) AND 5-MERCAPTO-1-PHENYL-1,2,3,4-TETRAZOLE (MPTH), Polyhedron, 12(7), 1993, pp. 759-763
Reactions of [Cu(AsPh3)3X] with the title ligands yield [Cu(AsPh3)2(LH
)X] [GRAPHICS] These complexes have been characterized on the basis of
analytical, IR, electronic (UV-vis), H-1 NMR, conductivity and magnet
ic measurements. In all cases there is a distorted tetrahedral environ
ment around copper(I), and the ligands (LH) bind through the thione su
lphur atom to copper(I).