SUBSTITUTION-REACTIONS OF [CUI(ASPH3)3X] (X = CL, BR OR I) WITH 3-PHENYL-2-THIOXOIMIDAZOLIDIN-4-ONE (PTIH) AND 5-MERCAPTO-1-PHENYL-1,2,3,4-TETRAZOLE (MPTH)

Citation
R. Singh et Sk. Dikshit, SUBSTITUTION-REACTIONS OF [CUI(ASPH3)3X] (X = CL, BR OR I) WITH 3-PHENYL-2-THIOXOIMIDAZOLIDIN-4-ONE (PTIH) AND 5-MERCAPTO-1-PHENYL-1,2,3,4-TETRAZOLE (MPTH), Polyhedron, 12(7), 1993, pp. 759-763
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
ISSN journal
02775387
Volume
12
Issue
7
Year of publication
1993
Pages
759 - 763
Database
ISI
SICI code
0277-5387(1993)12:7<759:SO[(=C>2.0.ZU;2-J
Abstract
Reactions of [Cu(AsPh3)3X] with the title ligands yield [Cu(AsPh3)2(LH )X] [GRAPHICS] These complexes have been characterized on the basis of analytical, IR, electronic (UV-vis), H-1 NMR, conductivity and magnet ic measurements. In all cases there is a distorted tetrahedral environ ment around copper(I), and the ligands (LH) bind through the thione su lphur atom to copper(I).