SYNTHESES AND CRYSTAL-STRUCTURES OF 3-POLYMERIC CLUSTER COMPOUNDS [AGMOS4.ALPHA-MEPYH]N, [AGMOS4.GAMMA-MEPYH]N AND [AGWS4.GAMMA-MEPYH]N

Authors
LANG JP LI JG BAO SA XIN XQ YU KB
Citation
Jp. Lang et al., SYNTHESES AND CRYSTAL-STRUCTURES OF 3-POLYMERIC CLUSTER COMPOUNDS [AGMOS4.ALPHA-MEPYH]N, [AGMOS4.GAMMA-MEPYH]N AND [AGWS4.GAMMA-MEPYH]N, Polyhedron, 12(7), 1993, pp. 801-806
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
12
Issue
7
Year of publication
1993
Pages
801 - 806
Database
ISI
SICI code
0277-5387(1993)12:7<801:SACO3C>2.0.ZU;2-U
Abstract
The title compounds were obtained by reacting (NH4)2MS4 (M = Mo, W) an d AgI with excess alpha-methylpyridine or gamma-methylpyridine. The st ructures can be described as extended networks of -AgS2M- (M = MO, W) as four-membered rhombs which are alternately parallel and perpendicul ar all along the polymer chain composed of continuous metal-metal bond s.