Gk. Bichile et al., ENHANCED FLUX-PINNING AND CRITICAL CURRENTS BY V-SUBSTITUTION IN YBA2CU3O7-DELTA, Superconductor science and technology, 6(4), 1993, pp. 233-237
V substituted samples with stoichiometric composition YBa2(Cu1-xVx)3O7
-delta, Where 0 < x < 0.04, prepared under identical conditins have be
en characterized by resistivity, AC susceptibility and DC magnetizatio
n measurements. DC magnetization measurements on randomly-oriented pow
dered systems, as a function of temperature and field, exhibit pronoun
ced M(H) hysteresis loops, indicative of large flux pinning even as T
approaches T(c). We feel that this flux pinning arises due to the pref
erential substitution of V on the Cu(I) site, which acts as a pinning
centre. A critical current density, J(c), of approximately 7.4 x 10(5)
A cm-2 is deduced from M(H) data at T = 13 K in an 8 kOe field for sa
mples with x = 0.01, 0.02 and 0.04, which is nearly seven times higher
than the J(c) of the pristine 1-2-3 powdered sample.