CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(PYRIDINE)BIS(TRIFLUOROMETHYL)ZINC

Authors
BEHM J LOTZ SD HERRMANN WA
Citation
J. Behm et al., CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(PYRIDINE)BIS(TRIFLUOROMETHYL)ZINC, Zeitschrift fur anorganische und allgemeine Chemie, 619(5), 1993, pp. 849-852
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
619
Issue
5
Year of publication
1993
Pages
849 - 852
Database
ISI
SICI code
0044-2313(1993)619:5<849:CAMOB>2.0.ZU;2-U
Abstract
Bis(pyridin)bis(trifluoromethyl)zinc 1 has been isolated and character ized by means of single-crystal X-ray diffraction techniques. The titl e compound represents the first structure determination of a fully flu orinated alkylzinc compound (monoclinic, space group P2(1)/c, Z = 4, a = 8.856(3), b = 18.158(3), c = 8.979(3) angstrom, beta = 98.14(2)degr ees, R = 0.054, R(w) = 0.035). The zinc atom is in a distorted tetrahe dral environment. The molecular structure of [ClZn(CCl2CF3) . Et2O]2 w as solved, but is not included in a structural comparison due to cryst allographic disorder.