FORMATION OF LIVING POLY(VINYL PYRIDINE) CHAINS WITH CHROMIUM COUNTERION AND THEIR USE FOR THE SYNTHESIS OF HYBRID POLYMERS

Authors
FEDOROVA LA BARANOVSKAYA IA TURKOVA LD KLENIN SI ERUSSALIMSKY BL
Citation
La. Fedorova et al., FORMATION OF LIVING POLY(VINYL PYRIDINE) CHAINS WITH CHROMIUM COUNTERION AND THEIR USE FOR THE SYNTHESIS OF HYBRID POLYMERS, Pure and applied chemistry, A30, 1993, pp. 261-270
Citations number
7
Categorie Soggetti
Polymer Sciences
Journal title
Pure and applied chemistry → ACNP
ISSN journal
00334545
Volume
A30
Year of publication
1993
Supplement
3-4
Pages
261 - 270
Database
ISI
SICI code
0033-4545(1993)A30:<261:FOLPPC>2.0.ZU;2-6
Abstract
Tris-T1-allyl chromium being inactive with respect to vinyl pyridines at 0-degrees-C, induces effective polymerization of 2- and 4-vinyl pyr idines at 50-60-degrees-C. The living chains formed in these processes are able to initiate the polymerization of acrylonitrile and methyl m ethacrylate, i.e. to form the corresponding copolymers.