DIELS-ALDER REACTION OF CYCLOPENTADIENE AND SPIROEPOXY-2,4-CYCLOHEXADIENONES

Authors
GESSON JP HERVAUD L MONDON M
Citation
Jp. Gesson et al., DIELS-ALDER REACTION OF CYCLOPENTADIENE AND SPIROEPOXY-2,4-CYCLOHEXADIENONES, Tetrahedron letters, 34(18), 1993, pp. 2941-2944
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
18
Year of publication
1993
Pages
2941 - 2944
Database
ISI
SICI code
0040-4039(1993)34:18<2941:DROCAS>2.0.ZU;2-2
Abstract
Diels-Alder reaction of cyclopentadiene with spiroepoxycyclohexadienon es obtained by Adler oxidation of salicyl alcohols affords mainly endo -endo adducts. Cope rearrangement of normal-electron-demand adducts an d endo-endo inverse-electron-demand addition of 2a with ethylvinyl eth er are also shown.