A COMPOUND PREVIOUSLY DESCRIBED AS TRICHLOROMETHANETHIOL IS IN FACT 1,1,2,2-TETRACHLORO-1,2-ETHANEDISULFENYL DICHLORIDE

Authors
NIELSEN SB SENNING A
Citation
Sb. Nielsen et A. Senning, A COMPOUND PREVIOUSLY DESCRIBED AS TRICHLOROMETHANETHIOL IS IN FACT 1,1,2,2-TETRACHLORO-1,2-ETHANEDISULFENYL DICHLORIDE, Tetrahedron letters, 34(18), 1993, pp. 2973-2974
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
18
Year of publication
1993
Pages
2973 - 2974
Database
ISI
SICI code
0040-4039(1993)34:18<2973:ACPDAT>2.0.ZU;2-W
Abstract
The reaction of N-(4-methylphenyl)-trichloromethanesulfenamide 2a with base gives yl-phenyl)-5,5,6,6-tetrachloro-2,3,5,6-tetrahydro- 1.4,2,3 -dithiadiazine 6a, which can be cleaved with HCI to give 1.1,2,2-tetra chloro-1,2-ethanedisulfenyl chloride 7, and not, respectively, trachlo ro-2,3,5,6-tetrahydro-1,4,2,5-dithiadiazine 4a and trichloromethanethi ol S.