BASE HYDROLYSIS OF TRIS(ACETYLACETONATO)METAL(III) COMPLEXES INVOLVING TECHNETIUM AND RUTHENIUM

Authors
MUTALIB A OMORI T YOSHIHARA K
Citation
A. Mutalib et al., BASE HYDROLYSIS OF TRIS(ACETYLACETONATO)METAL(III) COMPLEXES INVOLVING TECHNETIUM AND RUTHENIUM, Journal of radioanalytical and nuclear chemistry, 170(1), 1993, pp. 67-77
Citations number
17
Categorie Soggetti
Chemistry Analytical","Nuclear Sciences & Tecnology","Chemistry Inorganic & Nuclear
Journal title
Journal of radioanalytical and nuclear chemistry → ACNP
ISSN journal
02365731
Volume
170
Issue
1
Year of publication
1993
Pages
67 - 77
Database
ISI
SICI code
0236-5731(1993)170:1<67:BHOTCI>2.0.ZU;2-C
Abstract
Base hydrolysis of Tc(acac)3 and Ru(acac)3 was studied in 0.1-1M NaOH at different temperatures. In spite of apparent similarity of these co mplexes Tc(acac)3 showed more complexity than Ru(acac)3 in kinetic beh avior. Tc(acac)3 decomposes with a rate, d[Tc(acac)3]/dt = (k1[OH-] + k2[OH-]2)[Tc(acac)3], where k1 and k2 at 25-degrees-C are (1.67 +/- 0.11) x 10(-5) mol-1 . s-1 and (1.71 +/- +/- 0.14) x 10(-5) mol-1 . s- 1, respectively. Decomposition of Ru(acac)3 is expressed by the rate e quation d[Ru(acac)3]/dt = k[OH-][Ru(acac)3], where k at 37-degrees-C i s (8.01 +/- 0.23) x 10(-6) mol-2 . s-1.