SIMULTANEOUS DETERMINATION OF URANIUM AND THORIUM USING 4-(2'-THIAZOLYLAZO)RESACETOPHENONE OXIME AS ANALYTICAL REAGENT - A DERIVATIVE SPECTROPHOTOMETRIC METHOD

Citation
A. Ramesh et al., SIMULTANEOUS DETERMINATION OF URANIUM AND THORIUM USING 4-(2'-THIAZOLYLAZO)RESACETOPHENONE OXIME AS ANALYTICAL REAGENT - A DERIVATIVE SPECTROPHOTOMETRIC METHOD, Journal of radioanalytical and nuclear chemistry, 170(1), 1993, pp. 181-187
Citations number
8
Categorie Soggetti
Chemistry Analytical","Nuclear Sciences & Tecnology","Chemistry Inorganic & Nuclear
ISSN journal
02365731
Volume
170
Issue
1
Year of publication
1993
Pages
181 - 187
Database
ISI
SICI code
0236-5731(1993)170:1<181:SDOUAT>2.0.ZU;2-J
Abstract
A first derivative spectrophotometric method has been developed for th e simultaneous determination of uranium(VI) and thorium(IV) when prese nt in the same solution using 4-(2'-tiazolylazo)resacetophenone oxime (TARPO) as analytical reagent without prior separation of any of the m etals or using masking agents, etc. The method allows the determinatio n of uranium and thorium in their mixtures in the range of 0-10 ppm ea ch. Many common anions and cations even in large quantities do not int erfere.